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Hybridization in MLk (k>2) Systems

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成果类型:
期刊论文
作者:
LIU, F*;ZHAN, CG
通讯作者:
LIU, F
作者机构:
Department of Chemistry, Central China Normal University, Wuhan, People's Republic of China
通讯机构:
[LIU, F] C
CENT CHINA NORMAL UNIV,DEPT CHEM,WUHAN,PEOPLES R CHINA.
语种:
英文
期刊:
CROATICA CHEMICA ACTA
ISSN:
0011-1643
年:
1990
卷:
62
期:
4
页码:
695-703
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
This paper describes a generalized and extended treatment of the preceding papers in which the maximum overlap method was employed but the results were limited by the. condition that the number of Iigands surrounding the central atom should be two, that is, k = 2 in molecule MLko Based on the special assumption. that the angles < LpMLq = a between any two M-Lj bonds in molecule MLk are equal, many general formula s related to the diagonal matrix D (Jo), unitary matrix U", overlap matrix Sl and the bond strength F a...

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