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Visible light-driven photocatalytic generation of sulfonamidyl radicals for alkene hydroamination of unsaturated sulfonamides

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成果类型:
期刊论文
作者:
Chen, Jun;Guo, Hong-Mei;Zhao, Quan-Qing;Chen, Jia-Rong*;Xiao, Wen-Jing
通讯作者:
Chen, Jia-Rong
作者机构:
[Zhao, Quan-Qing; Guo, Hong-Mei; Xiao, Wen-Jing; Chen, Jun; Chen, Jia-Rong] Cent China Normal Univ, CCNU uOttawa Joint Res Ctr, Hubei Int Sci & Technol Cooperat Base Pesticide &, Key Lab Pesticide & Chem Biol,Minist Educ,Coll Ch, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China.
[Xiao, Wen-Jing] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.
通讯机构:
[Chen, Jia-Rong] C
Cent China Normal Univ, CCNU uOttawa Joint Res Ctr, Hubei Int Sci & Technol Cooperat Base Pesticide &, Key Lab Pesticide & Chem Biol,Minist Educ,Coll Ch, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China.
语种:
英文
期刊:
Chemical Communications
ISSN:
1359-7345
年:
2018
卷:
54
期:
50
页码:
6780-6783
基金类别:
NNSFCNational Natural Science Foundation of China (NSFC) [21622201, 21472058, 21472057, 21772053]; Distinguished Youth Foundation of Hubei Province [2016CFA050]; CCNU [CCNU17TS0011, CCNU16JCZX02]; Program of Introducing Talents of Discipline to Universities of China (111 Program) [B17019]
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
A visible light-driven photocatalytic generation of sulfonamidyl radicals, and application to intramolecular alkene hydroamination, has been accomplished, providing a mild and efficient approach to various functionalized isoxazolidines. The success of this protocol is based on the strategy of oxidative deprotonation electron transfer by merging the base and the photocatalyst under visible light irradiation, obviating installation of a photo...

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