Visible-Light-Promoted Transition-Metal-Free Phosphinylation of Heteroaryl Halides in the Presence of Potassium tert-Butoxide

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成果类型：

期刊论文

作者：

Yuan, Jia;To, Wai-Pong;Zhang, Zi-Yang;Yue, Chang-Duo;Meng, Sixuan;...

通讯作者：

Yu, Guang-Ao;Che, Chi-Ming

作者机构：

[Zhang, Zi-Yang; Yuan, Jia; Meng, Sixuan; Yu, Guang-Ao; Chen, Jian; Yue, Chang-Duo] Cent China Normal Univ, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Hubei, Peoples R China.

[Zhang, Zi-Yang; Yuan, Jia; Meng, Sixuan; Yu, Guang-Ao; Chen, Jian; Yue, Chang-Duo] Cent China Normal Univ, Int Joint Res Ctr Intelligent Biosensing Technol, Hubei Int Sci & Technol Cooperat Base Pesticide &, Chem Biol Ctr,Coll Chem, Wuhan 430079, Hubei, Peoples R China.

[Che, Chi-Ming; To, Wai-Pong] Univ Hong Kong, State Key Lab Synthet Chem, Pokfulam Rd, Hong Kong, Peoples R China.

[Che, Chi-Ming; To, Wai-Pong] Univ Hong Kong, Dept Chem, Pokfulam Rd, Hong Kong, Peoples R China.

[Liu, Yungen] South Univ Sci & Technol, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China.

通讯机构：

[Yu, Guang-Ao] C

[Che, Chi-Ming] U

Cent China Normal Univ, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Hubei, Peoples R China.

Cent China Normal Univ, Int Joint Res Ctr Intelligent Biosensing Technol, Hubei Int Sci & Technol Cooperat Base Pesticide &, Chem Biol Ctr,Coll Chem, Wuhan 430079, Hubei, Peoples R China.

Univ Hong Kong, State Key Lab Synthet Chem, Pokfulam Rd, Hong Kong, Peoples R China.

语种：

英文

期刊：

Organic Letters

ISSN：

1523-7060

年：

2018

卷：

期：

页码：

7816-7820

DOI：

10.1021/acs.orglett.8b03265

基金类别：

National Natural Science Foundation of ChinaNational Natural Science Foundation of China [21472060, 21772058, 21072071]; Program of Introducing Talents of Discipline to Universities of China (111 Program) [B17019]; CCNU from the colleges' basic research and operation of MOE [CCNU17QN011, CCNU17CG0011, CCNU17KYZHSY07, CCNU18KYZHSY06]; China Postdoctoral Science FoundationChina Postdoctoral Science Foundation [2018M632898]

机构署名：

本校为第一且通讯机构

院系归属：

化学学院

摘要：

A novel visible-light-promoted C–P bond formation reaction in the absence of both transition metal and photoredox catalysts is disclosed. By employing easily available and inexpensive heteroaryl chlorides/bromides as substrates, a variety of heteroaryl phosphine oxides were obtained in moderate to good yields. This strategy provides a simple and efficien...

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Visible-Light-Promoted Transition-Metal-Free Phosphinylation of Heteroaryl Halides in the Presence of Potassium tert-Butoxide

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