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Fe@Fe2O3 promoted electrochemical mineralization of atrazine via a triazinon ring opening mechanism

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成果类型:
期刊论文
作者:
Ding, Xing;Wang, Shengyao;Shen, Wanqiu;Mu, Yi;Wang, Li;...
通讯作者:
Zhang, Lizhi;Chen, Hao
作者机构:
[Zhang, Lizhi; Wang, Li; Ding, Xing; Shen, Wanqiu; Mu, Yi] Cent China Normal Univ, Inst Environm & Appl Chem, Coll Chem, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Peoples R China.
[Ding, Xing; Wang, Shengyao; Chen, Hao] Huazhong Agr Univ, Coll Sci, Wuhan 430070, Peoples R China.
[Wang, Li] Hubei Engn Univ, Coll Chem & Mat Sci, Xiaogan 432000, Peoples R China.
通讯机构:
[Zhang, Lizhi] C
[Chen, Hao] H
Cent China Normal Univ, Inst Environm & Appl Chem, Coll Chem, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Peoples R China.
Huazhong Agr Univ, Coll Sci, Wuhan 430070, Peoples R China.
语种:
英文
关键词:
*Atrazine;*Boron-doped diamond;*Electrochemical advanced oxidation;*Fe@Fe(2)O(3)/ACF electrode;*Fenton
期刊:
Water Research
ISSN:
0043-1354
年:
2017
卷:
112
页码:
9-18
基金类别:
Natural Science Funds for Distinguished Young ScholarsNational Natural Science Foundation of China (NSFC)National Science Fund for Distinguished Young Scholars [21425728]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51572101, 21607047, 21407044]; Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities [2015QD047, 2016PY088, 2015PY120, 2015PY047]; Natural Science Foundation of Hubei ProvinceNatural Science Foundation of Hubei Province [2016CFB193]
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
In this study, an electrochemical/electro-Fenton oxidation (EC/EF) system was designed to degrade atrazine, by utilizing boron-doped diamond (BDD) and Fe@Fe2O3 core-shell nanowires loaded active carbon fiber (Fe@Fe2O3/ACF) as the anode and the cathode, respectively. This EC/EF system exhibited much higher degradation rate, decholorination and mineralization efficiency of atrazine than the electrochemical (EC) and electrochemical/traditional electro-Fenton (EC/TEF) oxidation counterpart systems without Fe@Fe2O3 core-shell nanowires. Active species trapping experiment revealed that Fe@Fe2O3 coul...

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