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Novel furo[2,3-d] pyrimidine derivative as fluorescent chemosensor for HSO4-

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成果类型:
期刊论文
作者:
Xue, Weijian;Li, Lin;Li, Qi;Wu, Anxin*吴安心
通讯作者:
Wu, Anxin(吴安心
作者机构:
[Wu, Anxin; Xue, Weijian; Li, Lin; Li, Qi] Cent China Normal Univ, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
[Wu, Anxin] Cent China Normal Univ, Minist Educ, Key Lab Pesticide & Chem Biol, 152 Luoyu Rd, Wuhan 430079, Peoples R China.
通讯机构:
[Wu, Anxin] C
Cent China Normal Univ, Minist Educ, Key Lab Pesticide & Chem Biol, 152 Luoyu Rd, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
Fluorescent chemosensor;HSO4- ion;Selectivity;Sonogashira reaction
期刊:
Talanta
ISSN:
0039-9140
年:
2012
卷:
88
页码:
734-738
基金类别:
PCSIRTProgram for Changjiang Scholars & Innovative Research Team in University (PCSIRT) [IRT 0953]; Doctor Independent Foundation of Central China Normal University [2009007]
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
A class of novel heterocyclic compounds 1a-1c has been designed and synthesized. And our initial discovery is that these compounds can effectively recognize HSO4-. With the addition of HSO4 -, a new energy band appears at 360-390 nm in the absorption spectra. The emission spectrum (λex = 328 nm) undergoes an important change in its fluorescent effect in the presence of HSO4-. All available data (absorption and emission) strongly support the formation of hydrogen-bonded complexes between 1a and 1c and HSO4-. ©2011 Elsevier B.V. All rights reserved.

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