1,1,3,3- tetrabenzyl- 2,4,5- trithiole was prepared in solvent ether absolute with 1,3 -diph-enyl-2,2-dithiol and iodine as raw materials using acetic anhydride as catalyst, the yield of 1,1,3,3- tetrabenzyl- 2,4,5- trithiole was 82.50/40, The thermal properties of 1,1,3,3 -tetrabenzyl -2,4,5-trithiole was studied by DSC and TG method from 50℃ to 500℃ in the static. Hearing rate wae 10℃/min in the experiments. The results shows that can be oxidized over 257.1℃ in air. Therefore, it should be preserved under 257.1℃. And it c...