期刊论文

中文

合成化学

1005-1511

2003

11

4

331-333

10.3969/j.issn.1005-1511.2003.04.011

国家自然科学基金资助项目 （2 0 10 2 0 0 1）； 湖北省教育厅重点科研基金资助项目（2 0 0 3 A0 0 2 ）；

本校为其他机构

应用烯基膦亚胺与二硫化碳、一级脂肪胺的串联aza—Wittig反应合成了2-硫代-3-烷基-5-苯基亚甲基-4-咪唑啉二酮衍生物。提出了可能的环化反应机理，探讨了所合成化合物的成环反应条件和波谱性质。经元素分析、IR，~1H NMR和MS确证产物均为新化合物。

2-Thio 3 alkyl 5 phenylmethylidene 4 imidazolidinones were synthesized via tandem aza Wittig reaction of vinyliminophosphorane, carbon disufide and aliphatic primary amines. A possible mechanism for the cyclization reaction was put forward, and the spectral properties and the condition for cyclization of the synthesized compounds were researched. All the cyclized products are new, and their structures are c...