Science and Technology Plan Projects of Sichuan [2018JY0275]; Scientific Research Funded Projects of the Education Department of Sichuan [18ZB0458]; Young Teachers Funded Projects of Sichuan Agricultural University [03120310]
机构署名:
本校为通讯机构
院系归属:
化学学院
摘要:
We investigated the permselectivity and interfacial electron transfers of an amphiphilic branch-tailed fluorosurfactant self-assembled monolayer (FS-SAM) on a gold electrode by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The FS-SAM was prepared by a self-assembly technique and a “click” reaction. The barrier property and interfacial electron transfers of the FS-SAM were also evaluated using various probes with different features. The FS-SAM allowed a higher degree of permeation by small hydrophilic (Cl − and F −...