Synthesis, Structure, and Magnetic Properties of a New 2D Cobalt(II) Metal-organic Framework

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成果类型：

期刊论文

作者：

Chen Xu-Xing;Li Rong;Wang Shuai-Hua;Cai Li-Zhen;Yi Zhi-Guo*;...

通讯作者：

Huang Xin-Tang;Yi Zhi-Guo

作者机构：

[Chen Xu-Xing; Huang Xin-Tang] Cent China Normal Univ, Dept Phys, Inst Nanosci & Nanotechnol, Wuhan 430079, Hubei, Peoples R China.

[Wang Shuai-Hua; Cai Li-Zhen; Chen Xu-Xing; Li Rong; Yi Zhi-Guo] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China.

[Chen Xu-Xing] Hubei Normal Univ, Inst Adv Mat, Huangshi 435002, Hubei, Peoples R China.

[Chen Xu-Xing] Hubei Normal Univ, Sch Phys & Elect Sci, Huangshi 435002, Hubei, Peoples R China.

通讯机构：

[Huang Xin-Tang; Yi Zhi-Guo] C

Cent China Normal Univ, Dept Phys, Inst Nanosci & Nanotechnol, Wuhan 430079, Hubei, Peoples R China.

Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China.

语种：

英文

关键词：

cobalt metal-organic framework;hydrothermal reaction;crystal structure;magnetic property

关键词(中文)：

磁性材料;金属有机;钴(Ⅱ);水热合成;骨架材料;二维;单晶X射线衍射分析;结构

期刊：

Chinese Journal of Structural Chemistry

ISSN：

0254-5861

年：

2017

卷：

期：

页码：

1375-1380

DOI：

10.14102/j.cnki.0254-5861.2011-1512

基金类别：

National Key Project on Basic ResearchNational Basic Research Program of China [2013CB933203]; Chinese Academy of SciencesChinese Academy of Sciences [XDB20000000]; Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21373224, 21577143, 51502289]; Natural Science Foundation of Fujian ProvinceNatural Science Foundation of Fujian Province [2014H0054, 2015J05044]; Chinese Academy of SciencesChinese Academy of Sciences

机构署名：

本校为第一且通讯机构

院系归属：

物理科学与技术学院

摘要：

Rational design of magnetic materials with desired magnetic properties has attracted wide interest in recent decades. Herein, we present a new 2D cobalt(II) metal-organic framework, namely [Co(MQ)_2(V_2O_6)_2]_n·4 nH_2O 1, which was hydrothermally synthesized by the reaction of Co(NO_3)_2·4H_2O, N-methyl-4,4′-bipyridinium (MQ+) chlorine salt and NH_4VO_3. Single-crystal X-ray diffraction analysis reveals that 1 crystallizes in C2/c space group with a = 16.290(5), b = 7.815(2), c = 25.297(7) A, β = 108.459(5)°, V = 3054.8(15) A~3, Z = 4, D_...

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Synthesis, Structure, and Magnetic Properties of a New 2D Cobalt(II) Metal-organic Framework

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