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Stable structure and fast ion diffusion: N-doped VO2 3D porous nanoflowers for applications in ultrafast rechargeable aqueous zinc-ion batteries

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成果类型:
期刊论文
作者:
Hao, Kunyu;Sheng, Zhuwei;Qi, Pengcheng;Lu, Yu;Liu, Gaofu;...
通讯作者:
Tang, YW
作者机构:
[Chen, Mingyue; Tang, Yiwen; Qi, Pengcheng; Liu, Gaofu; Wu, Hao; Sheng, Zhuwei; Tang, YW; Hao, Kunyu; Lu, Yu] Cent China Normal Univ, Inst Nanosci & Technol, Coll Phys Sci & Technol, Wuhan 430079, Peoples R China.
通讯机构:
[Tang, YW ] C
Cent China Normal Univ, Inst Nanosci & Technol, Coll Phys Sci & Technol, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
Cathodes;Diffusion;Doping (additives);Electric conductivity;Lithium-ion batteries;Thermooxidation;Vanadium dioxide;Zeolites;Zinc;Electrical conductivity;Fast ions;Ion batteries;Ions diffusion;N-doped;Thermal-oxidation;Ultra-fast;Ultrafast charging;Zinc ions;Zinc-ion battery;Ions;ammonium vanadate;imidazole;nanoflower;oxide;vanadium;zeolite;zinc ion;aqueous solution;Article;chemical structure;current density;cyclic voltammetry;diffusion;electric conductivity;electrochemistry;energy;impedance spectroscopy;molecular interaction;molecular stability;oxidation;power supply;precursor;storage;synthesis;X ray powder diffraction
期刊:
Journal of Colloid and Interface Science
ISSN:
0021-9797
年:
2023
卷:
644
页码:
275-284
基金类别:
The authors acknowledge the financial support of the National Natural Science Foundation of China (Grant No. 51972133 , 51572102 ).
机构署名:
本校为第一且通讯机构
院系归属:
物理科学与技术学院
摘要:
Aqueous rechargeable zinc-ion batteries (ARZIBs) are promising candidates for fast-charging energy-storage systems. The issues of stronger interactions between Zn2+ and the cathode for ultrafast ARZIBs can be partially addressed by enhancing mass transfer and ion diffusion of the cathode. Herein, via thermal oxidation for the first time, N-doped VO2 porous nanoflowers with short ion diffusion paths and improved electrical conductivity were synthesized as ARZIBs cathode materials. The introduction of nitrogen derived from the vanadium-based-zeol...

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