[Feng, Lizhen; Zhang, Lizhi; Gong, Jingming; Yuan, Yijin; Wu, Mengsi; He, Xianqin] Cent China Normal Univ, Int Joint Res Ctr Intelligent Biosensing Technol, Coll Chem,Minist Educ, Inst Environm & Appl Chem,Key Lab Pesticide & Che, Wuhan 430079, Peoples R China.
通讯机构:
[Lizhi Zhang; Jingming Gong] K
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Environmental & Applied Chemistry, International Joint Research Center for Intelligent Biosensing Technology and Health, College of Chemistry, Central China Normal University, Wuhan 430079, China
National Science Foundation of China [22076057, 21777052]; National Key R&D Program of China [2018YFC1802003]; Project for Application Foundation Frontier for Wuhan [2019020701011486]; Program of Introducing Talents of Discipline to Universities of China (111 program) [B17019]
机构署名:
本校为第一机构
院系归属:
化学学院
摘要:
Sulfite (S(IV)) is a promising substitute for sulfate radical-based advanced oxidation processes. Here, a composite of in-situ anchoring NiCo2O4 nanosheets on biochar (BC) was firstly employed as a heterogeneous activator for sulfite (NiCo2O4@BC-sulfite) to degrade atrazine (ATZ) in the neutral environment. The synergistic coupling of BC and NiCo2O4 endows the resulting composite excellent catalytic activity. 82% of the degradation ratio of ATZ (1 mg/L) could be achieved within 10 min at initial concentrations of 0.6 g/L NiCo2O4@BC, 3.0 mmol/L sulfite in neutral environment. When further suppl...