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Oxalate modification enabled advanced phosphate removal of nZVI: In Situ formed surface ternary complex and altered multi-stage adsorption process

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成果类型:
期刊论文
作者:
Cao, Shiyu;Li, Jiangshan;Shi, Yanbiao;Guo, Furong;Gao, Tingjuan;...
通讯作者:
Tingjuan Gao<&wdkj&>Lizhi Zhang
作者机构:
[Guo, Furong; Gao, Tingjuan] Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Environmental & Applied Chemistry, College of Chemistry, Central China Normal University, Wuhan 430079, China
School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
[Li, Jiangshan] State Key Laboratory of Geomechanics and Geotechnical Engineering, Institute of Rock and Soil Mechanics, Chinese Academy of Sciences, Wuhan 430071, China
[Cao, Shiyu] Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Environmental & Applied Chemistry, College of Chemistry, Central China Normal University, Wuhan 430079, China<&wdkj&>State Key Laboratory of Geomechanics and Geotechnical Engineering, Institute of Rock and Soil Mechanics, Chinese Academy of Sciences, Wuhan 430071, China
[Shi, Yanbiao; Zhang, Lizhi] Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Environmental & Applied Chemistry, College of Chemistry, Central China Normal University, Wuhan 430079, China<&wdkj&>School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
通讯机构:
[Tingjuan Gao; Lizhi Zhang] K
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Environmental & Applied Chemistry, College of Chemistry, Central China Normal University, Wuhan 430079, China<&wdkj&>School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China<&wdkj&>Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Environmental & Applied Chemistry, College of Chemistry, Central China Normal University, Wuhan 430079, China
语种:
英文
关键词:
Iron compounds;Oxalic acid;Passivation;Adsorption site;Advanced phosphate removal;Multi-stage adsorption;Multi-stages;Nano zero-valent iron;Nano zero-valent irons;Oxalate modification;Phosphate removal;Surface ternary complex;Ternary complex;Adsorption;adsorption;iron nanoparticle;oxalate;phosphate;pollutant removal
期刊:
环境科学学报(英文版)
ISSN:
1001-0742
年:
2025
卷:
149
页码:
79-87
基金类别:
This work was supported by the National Key Research and Development Program of China (Nos. 2022YFA1205602 , and 2023YFC3707801 ), the National Natural Science Foundation of China (Nos. U22A20402 , 22376073 , 21936003 and 22306119 ), and the China Postdoctoral Science Foundation (No. 2023T160419 ).
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
Nano zero-valent iron (nZVI) is a promising phosphate adsorbent for advanced phosphate removal. However, the rapid passivation of nZVI and the low activity of adsorption sites seriously limit its phosphate removal performance, accounting for its inapplicability to meet the emission criteria of 0.1 mg P/L phosphate. In this study, we report that the oxalate modification can inhibit the passivation of nZVI and alter the multi-stage phosphate adsorption mechanism by changing the adsorption sites. As expected, the stronger anti-passivation ability ...

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