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Dithienylethene-bridged gold(I) isocyanide complexes: Synthesis, photochromism and “turn-on” fluorescent switching behavior

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成果类型:
期刊论文
作者:
Lu, Tao;Yang, Xiaofei;Wang, Xiao-Yan;Li, Ziyong*;Yin, Jun;...
通讯作者:
Liu, Sheng Hua;Li, Ziyong
作者机构:
[Liu, Sheng Hua; Yang, Xiaofei; Wang, Xiao-Yan; Yin, Jun; Lu, Tao] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
[Li, Ziyong] Luoyang Normal Univ, Coll Food & Drug, Luoyang Key Lab Organ Funct Mol, Luoyang 471934, Peoples R China.
[Liu, Sheng Hua] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China.
通讯机构:
[Liu, Sheng Hua] C
[Li, Ziyong] L
Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
Luoyang Normal Univ, Coll Food & Drug, Luoyang Key Lab Organ Funct Mol, Luoyang 471934, Peoples R China.
语种:
英文
关键词:
Dithienylethene;gold(I);Isocyanide;Photochromism;“Turn-on” fluorescent switching
期刊:
Dyes and Pigments
ISSN:
0143-7208
年:
2021
卷:
185
页码:
108933
基金类别:
The authors acknowledge financial support from National Natural Science Foundation of China (No. 21472059 , 21772054 ).
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
Developing novel photochromic complexes based on dithienylethene is highly desirable for potential application in the fields of photoresponsive optoelectronics. In this contribution, four novel dithienylethene-bridged gold(I) isocyanide complexes 1a-1d have been designed and prepared by appending alkynyl-gold(I)-isocyanide triads at the termini of dithienylethene unit. They were fully characterized and confirmed by 1H NMR, 13C NMR, and HRMS (MALDI). Moreover, investigation on photochromic properties indicated that these complexes had good photo...

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