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Practical heterogeneous photoredox/nickel dual catalysis for C-N and C-O coupling reactions.

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成果类型:
期刊论文
作者:
Liu, Yi-Yin;Liang, Dong;Lu, Liang-Qiu*;Xiao, Wen-Jing
通讯作者:
Lu, Liang-Qiu
作者机构:
[Lu, Liang-Qiu; Xiao, Wen-Jing; Liang, Dong; Liu, Yi-Yin] Cent China Normal Univ, Coll Chem, Key Lab Pesticide Sc Chem Biol, Minist Educ,CCNU uOttawa Joint Res Ctr, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China.
[Lu, Liang-Qiu] Chinese Acad Sci, LICP, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China.
[Xiao, Wen-Jing] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China.
通讯机构:
[Lu, Liang-Qiu] C
Cent China Normal Univ, Coll Chem, Key Lab Pesticide Sc Chem Biol, Minist Educ,CCNU uOttawa Joint Res Ctr, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China.
Chinese Acad Sci, LICP, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China.
语种:
英文
期刊:
Chemical Communications
ISSN:
1359-7345
年:
2019
卷:
55
期:
33
页码:
4853-4856
基金类别:
National Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21822103, 21820102003, 21772052, 21772053, 21572074, 21472057]; Program of Introducing Talents of Discipline to Universities of China (111 Program) [B17019]; Natural Science Foundation of Hubei ProvinceNatural Science Foundation of Hubei Province [2017AHB047]; International Joint Research Center for Intelligent Biosensing Technology and Health
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
Efficient C-N and C-O coupling reactions of aryl halides with amines and alcohols have been developed by using the strategy of heterogeneous visible light photoredox and nickel dual catalysis. Obviously, the joint use of inexpensive and bench-stable CdS and nickel salts, together with mild reaction conditions, makes these two transformations attractive for the synthetic community. This heterogeneous dual catalysis system also proved to be successful in the ligand-free catalytic hydroxylation of aryl bromide with water as a nucleophile. The practicality of this protocol is further emphasized by...

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