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Photoinduced strategies towards strained molecules

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成果类型:
期刊论文
作者:
Mukund M. D. Pramanik;Hao Qian;Wen-Jing Xiao;Jia-Rong Chen
通讯作者:
Wen-Jing Xiao<&wdkj&>Jia-Rong Chen
作者机构:
[Mukund M. D. Pramanik; Hao Qian; Wen-Jing Xiao; Jia-Rong Chen] CCNU-uOttawa Joint Research Center, Key Laboratory of Pesticides & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079, China
通讯机构:
[Wen-Jing Xiao; Jia-Rong Chen] C
CCNU-uOttawa Joint Research Center, Key Laboratory of Pesticides & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079, China
语种:
英文
关键词:
Reaction kinetics;Cyclobutanes;Photo-induced;Propellanes;Radical reactions;Strained molecules;Molecules
期刊:
Organic Chemistry Frontiers
ISSN:
2052-4110
年:
2020
卷:
7
期:
17
页码:
2531-2537
基金类别:
Financial support of our own work in photochemistry from the NSFC (21971081, 91856119, 21820102003, and 91956201) is gratefully acknowledged.
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
New photoinduced strategies towards radical reactions of strained molecules such as [1.1.1]propellane and bicyclo[1.1.0]butanes by photoredox or metallaphotoredox catalysis have recently been disclosed. Such strategies enable the controllable construction of 1,3-difunctionalized bicyclo[1.1.1]pentanes, cyclobutanes, and drug-like analogues, and offer new opportunities for reaction design of [1.1.1]propellane and other stra...

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