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Pyrite enables persulfate activation for efficient atrazine degradation

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成果类型:
期刊论文
作者:
Wang, Xiaobing;Wang, Yueyao;Chen, Na;Shi, Yanbiao;Zhang, Lizhi*
通讯作者:
Zhang, Lizhi
作者机构:
[Zhang, Lizhi; Shi, Yanbiao; Wang, Xiaobing; Chen, Na; Wang, Yueyao] Cent China Normal Univ, Coll Chem, Inst Appl & Environm Chem, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Peoples R China.
通讯机构:
[Zhang, Lizhi] C
Cent China Normal Univ, Coll Chem, Inst Appl & Environm Chem, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
Atrazine degradation;Fe(III)/Fe(II) cycle;Iron-contained minerals;Persulfate activation;Pyrite
期刊:
Chemosphere
ISSN:
0045-6535
年:
2020
卷:
244
页码:
125568
基金类别:
National Key Research and Development Program of China [2018YFC1800701]; National Natural Science Funds for Distinguished Young ScholarsNational Natural Science Foundation of ChinaNational Science Fund for Distinguished Young Scholars [21425728]; National Science Foundation of ChinaNational Natural Science Foundation of China [21936003, 21872061]; 111 ProjectMinistry of Education, China - 111 Project [B17019]; CAS Interdisciplinary Innovation Team of the Chinese Academy of Sciences
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
Persulfate (PS) is widely used for environmental remediation, but its organic contaminant removal performance strongly depends on its activation. In this study, we demonstrate that pyrite (FeS2) can more effectively activate PS than the commonly used FeSO4 for atrazine degradation. When 3.0 mM of PS and 4.2 mM of iron salts were used, the atrazine degradation efficiency of FeS2/PS was 1.4 times that of FeSO4/PS, while the amount of consumed PS in case of FeS2 was only 53% of that by FeSO4. The better PS activation performance of FeS2 could be a...

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