期刊论文

Xiao, Wen-Jing;Koenig, Burkhard

英文

Chemical Communications

1359-7345

2019

55

1

107-110

10.1039/c8cc08362b

National Science Foundation of China [21822103, 21820102003, 21772052, 21772053, 21572074, 21472057]; Foundation for the Author of National Excellent Doctoral Dissertation of PR China [201422]; Natural Science Foundation of Hubei Province [2017AHB047]; German Science Foundation (DFG, Chemical Photocatalysis) [GRK 1626]

本校为第一且通讯机构

Two visible-light driven alkenylation reactions of unactivated alkyl bromides, which were enabled by the use of Ir(dF(CF3)ppy)2(dtbbpy)PF6 as the photocatalyst and (TMS)3SiH as the atom transfer reagent to activate the alkyl bromides, were described for the first time. These protocols can be used to produce a variety of alkenes from easily available feedstock with good reaction efficiency and high chemoselectivity under mild reaction conditions. To further demonstrate the applicability of the present strategy, the alkenylation of bioactive mole...