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Hydrogen Spillover to Oxygen Vacancy of TiO2- xHy/Fe: Breaking the Scaling Relationship of Ammonia Synthesis

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成果类型:
期刊论文
作者:
Mao, Chengliang;Wang, Jiaxian;Zou, Yunjie;Qi, Guodong;Loh, Joel Yi Yang;...
通讯作者:
Zhang, Lizhi;Ozin, Geoffrey A.
作者机构:
[Zhang, Lizhi; Zou, Yunjie; Liu, Xiao; Ai, Zhihui; Wang, Jiaxian; Mao, Chengliang; Shang, Huan; Zhao, Jincai; Li, Jie; Li, Meiqi] Cent China Normal Univ, Coll Chem, Inst Environm & Appl Chem, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Peoples R China.
[Ghoussoub, Mireille; Mao, Chengliang; Wang, Lu; Xia, Meikun; Ozin, Geoffrey A.] Univ Toronto, Dept Chem, Solar Fuels Cluster, Mat Chem & Nanochem Res Grp, Toronto, ON M5S 3H6, Canada.
[Qi, Guodong; Xu, Jun; Deng, Feng] Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Natl Ctr Magnet Resonance Wuhan, Wuhan Inst Phys & Math,Innovat Acad Precis Measur, Wuhan 430071, Peoples R China.
[Loh, Joel Yi Yang; Kherani, Nazir P.] Univ Toronto, Dept Mat Sci & Engn, Toronto, ON M5S 3E4, Canada.
[Zhang, Tianhua] Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC C, Sch Chem Engn, Fuzhou 350002, Fujian, Peoples R China.
通讯机构:
[Zhang, Lizhi] C
[Ozin, Geoffrey A.] U
Cent China Normal Univ, Coll Chem, Inst Environm & Appl Chem, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Peoples R China.
Univ Toronto, Dept Chem, Solar Fuels Cluster, Mat Chem & Nanochem Res Grp, Toronto, ON M5S 3H6, Canada.
语种:
英文
期刊:
Journal of the American Chemical Society
ISSN:
0002-7863
年:
2020
卷:
142
期:
41
页码:
17403-17412
基金类别:
Support for work in China came from National Natural Science Funds for Distinguished Young Scholars (21425728), National Key Research and Development Program of China (2016YFA0203002), National Science Foundation of China (51472100, 21872061), China Scholarship Council (CSC), and Excellent Doctoral Dissertation Cultivation Grant from Central China Normal University (2019YBZZ026). We also thank the National Supercomputer Center in Shenzhen for providing high-performance computation. Support for the work in Canada came from the Natural Sciences and Engineering Council of Canada (NSERC). Assistance in editing this manuscript was provided by Paul N. Duchesne, who acknowledges financial support from the NSERC Postdoctoral Fellowships program.
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
Optimizing kinetic barriers of ammonia synthesis to reduce the energy intensity has recently attracted significant research interest. The motivation for the research is to discover means by which activation barriers of N2 dissociation and NHz (z = 1-2, surface intermediates) destabilization can be reduced simultaneously, that is, breaking the "scaling relationship". However, by far only a single success has been reported in 2016 based on the discovery of a strong-weak N-bonding pair: transition metals (nitrides)-LiH. Described herein is a secon...

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