We report a highly effective growth of vertically aligned ZnO one-dimensional (1D) nanostructures on conducting alloy substrate (Fe-Co-Ni) in mild solutions (T &le 70°C) in the absence of any seeds, catalysts, and surfactants. The growth conditions such as NH3·H2O concentration, temperature, and nature of the substrate are correlated to affect the nanostructure formation. Different ZnO single-crystal nanostructures including nanoneedles, hexagonal nanorods, and nanopencils oriented normal to the substrate can be selectively formed in high quantity. The ordered ZnO nanostructures show...