National Key Research and Development Program of China [2016YFA0203000]; National Natural Science Funds for Distinguished Young ScholarsNational Natural Science Foundation of China (NSFC)National Science Fund for Distinguished Young Scholars [21425728]; National Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21477044]; Key Project of Natural Science Foundation of Hubei ProvinceNatural Science Foundation of Hubei Province [2013CFA114]; Self-Determined Research Funds of CCNU from the Colleges' Basic Research and Operation of MOE [CCNU14Z01001, CCNU14KFY002]; Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities [CCNU16A02029]; Excellent Doctoral Dissertation Cultivation Grant from Central China Normal University [2016YBZZ016]
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
In this study, we demonstrate that the bimetallic iron-nickel nanoparticles (nZVIN) possessed an enhanced performance in comparison with nanoscale zero-valent iron (nZVI) on aerobic degradation of 4-chlorophenol (4-CP). The 4-CP degradation rate constant in the aerobic nZVIN process (nZVIN/Air) was 5 times that in the classic nZVI counterpart system (nZVI/Air). Both reactive oxygen species measurement and inhibition experimental results suggested that hydroxyl radicals were the major active species contributed to aerobic 4-CP degradation with n...