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Phosphate Shifted Oxygen Reduction Pathway on Fe@Fe2O3 Core-Shell Nanowires for Enhanced Reactive Oxygen Species Generation and Aerobic 4-Chlorophenol Degradation

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成果类型:
期刊论文
作者:
Mu, Yi;Ai, Zhihui;Zhang, Lizhi*
通讯作者:
Zhang, Lizhi
作者机构:
[Zhang, Lizhi; Mu, Yi; Ai, Zhihui] Cent China Normal Univ, Inst Environm & Appl Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
通讯机构:
[Zhang, Lizhi] C
Cent China Normal Univ, Inst Environm & Appl Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
语种:
英文
期刊:
Environmental Science & Technology
ISSN:
0013-936X
年:
2017
卷:
51
期:
14
页码:
8101-8109
基金类别:
Natural Science Funds for Distinguished Young ScholarsNational Natural Science Foundation of China (NSFC)National Science Fund for Distinguished Young Scholars [21425728]; National Key Research and Development Program of China [2016YFA0203002]; 111 ProjectMinistry of Education, China - 111 Project [B17019]; CCNU from the Colleges' Basic Research and Operation of MOEMinistry of Education, Singapore [CCNU14Z01001, CCNU16A02029]; Central China Normal University [2015YBZD024, 2016YBZZ031]; CAS Interdisciplinary Innovation Team of the Chinese Academy of Sciences
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
Phosphate ions widely exist in the environment. Previous studies revealed that the adsorption of phosphate ions on nanoscale zerovalent iron would generate a passivating oxide shell to block reactive sites and thus decrease the direct pollutant reduction reactivity of zerovalent iron. Given that molecular oxygen activation process is different from direct pollutant reduction with nanoscale zerovalent iron, it is still unclear how phosphate ions will affect molecular oxygen activation and reactive oxygen species generation with nanoscale zeroval...

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