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A selective transformation of flavanones to 3-bromoflavones and flavones under microwave irradiation

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成果类型:
期刊论文
作者:
Zhou, ZZ;Zhao, PL;Huang, W;Yang, GF*杨光富
通讯作者:
Yang, GF(杨光富
作者机构:
[Yang, GF; Zhao, PL; Huang, W; Zhou, ZZ] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Coll Chem, Wuhan 430079, Peoples R China.
通讯机构:
[Yang, GF] C
Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Coll Chem, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
3-bromoflavones;N-bromosuccinimide;flavanones;flavones;microwave irradiation
期刊:
ADVANCED SYNTHESIS & CATALYSIS
ISSN:
1615-4150
年:
2006
卷:
348
期:
1-2
页码:
63-67
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
This paper presents the first report of a highly selective transformation of flavanones to 3-bromoflavones or flavones by microwave irradiation of the corresponding flavanone reactants and N-bromosuccinimide (NBS) in the presence of a catalytic amount of 2,2′-azobis(isobutyronitrile) (AIBN). The combination of good to excellent yields, shorter reaction time (10 min), and high levels of functional group compatibility make this an attractive synthetic approach to 3-bromoflavo...

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