期刊论文

Tunge, Jon A.

英文

Organic Letters

1523-7060

2018

20

7

1730-1734

10.1021/acs.orglett.8b00169

National Science FoundationNational Science Foundation (NSF) [CHE-1465172]; Kansas Bioscience Authority Rising Star program; China Scholarship Council (CSC)China Scholarship Council [201606770032]; NIHUnited States Department of Health & Human ServicesNational Institutes of Health (NIH) - USA [S10RR024664]; NSFNational Science Foundation (NSF) [1625923]; NATIONAL CENTER FOR RESEARCH RESOURCESUnited States Department of Health & Human ServicesNational Institutes of Health (NIH) - USANIH National Center for Research Resources (NCRR) [S10RR024664] Funding Source: NIH RePORTER; Direct For Mathematical & Physical ScienNational Science Foundation (NSF)NSF - Directorate for Mathematical & Physical Sciences (MPS) [1465172] Funding Source: National Science Foundation; Division Of ChemistryNational Science Foundation (NSF)NSF - Directorate for Mathematical & Physical Sciences (MPS) [1465172] Funding Source: National Science Foundation

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A palladium-catalyzed decarboxylative coupling of enol carbonates with diarylmethyl electrophiles that are derived from secondary benzylic alcohols has been developed. This method allows the generation of a variety of β-diaryl ketones through an efficient and highly stereospecific coupling. In addition, detailed mechanistic insight into the coupling suggests that the reaction is a rare example of an intramolecular decarboxylative coupling ...