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Molecularly imprinted polymers immobilized on graphene oxide film for monolithic fiber solid phase microextraction and ultrasensitive determination of triphenyl phosphate

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成果类型:
期刊论文
作者:
Jian, Yajing;Chen, Linfeng;Cheng, Jing*;Huang, Xiaolan;Yan, Ling;...
通讯作者:
Cheng, Jing;Li, Haibing
作者机构:
[Huang, Xiaolan; Jian, Yajing; Yan, Ling; Li, Haibing; Cheng, Jing; Li, HB; Chen, Linfeng] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Inst Environm Chem,Coll Chem, Wuhan 430079, Peoples R China.
通讯机构:
[Cheng, J; Li, HB] C
Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Inst Environm Chem,Coll Chem, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
Gas chromatography;Molecularly imprinted polymers immobilized on graphene oxide film;Monolithic fiber;Selective and ultrasensitive;Solid phase microextraction;Triphenyl phosphate
期刊:
Analytica Chimica Acta
ISSN:
0003-2670
年:
2020
卷:
1133
页码:
1-10
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21677058, 21772055]; 111 ProjectMinistry of Education, China - 111 Project [B17019]
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
Triphenyl phosphate (TPhP), a typical model of organophosphorus flame retardants (OPFRs), has been regarded as emerging environmental contaminants of health concern. In this study, TPhP molecularly imprinted polymers immobilized on graphene oxide (GO) film (TPhP-MIPs/GO) monolithic fiber for direct immersion solid phase microextraction (DI-SPME) was fabricated and evaluated. Compared with TPhP molecularly imprinted polymers (TPhP-MIPs) monolithic fiber, TPhP-MIPs/GO fiber had bigger extraction capacity, stronger hydrophilicity and faster mass transfer rate. Furthermore, TPhP-MIPs/GO fiber disp...

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