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Surface Molecularly Imprinted Polymer Film with Poly(p-aminothiophenol) Outer Layer Coated on Gold Nanoparticles Inner Layer for Highly Sensitive and Selective Sensing Paraoxon

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成果类型:
期刊论文
作者:
Li, Shanshan*;Luo, Qingying;Liu, Yaowen;Zhang, Zhiqing;Shen, Guanghui;...
通讯作者:
Li, Shanshan;Zhang, Aidong(张爱东
作者机构:
[Chen, Anjun; Liu, Xingyan; Liu, Yaowen; Luo, Qingying; Wu, Hejun; Li, Shanshan; Zhang, Zhiqing; Shen, Guanghui] Sichuan Agr Univ, Coll Food Sci, Yaan 625014, Peoples R China.
[Zhang, Aidong] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Hubei, Peoples R China.
通讯机构:
[Zhang, Aidong] C
[Li, Shanshan] S
Sichuan Agr Univ, Coll Food Sci, Yaan 625014, Peoples R China.
Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Hubei, Peoples R China.
语种:
英文
关键词:
molecularly imprinted polymer;surface molecularly imprinting;self-assembly directing;paraoxon;gold nanoparticles;electro-polymerization;electrochemical sensor
期刊:
Polymers
ISSN:
2073-4360
年:
2017
卷:
9
期:
8
页码:
359-
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21472064]; Young Teachers Funded Projects of Sichuan Agricultural University [03120310]
机构署名:
本校为通讯机构
院系归属:
化学学院
摘要:
This paper presents the fabrication of a molecularly imprinted, polymer-based disposable electrochemical sensor for paraoxon (PO) determination. The sensor was based on a screen-printed carbon electrode (SPCE) modified with a surface molecularly imprinted poly (p-aminothiophenol) (PATP)/gold nanoparticles (AuNPs) composite film, which consisted of a PATP outer layer and an AuNPs inner layer. We report a novel strategy, combining surface molecularly imprinting and self-assembly directed electro-polymerization with high densely imprinting PO molecules in the PATP/AuNPs film. Firstly, AuNPs were ...

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