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Sequential σ-Bond Insertion/Benzannulation Involving Arynes: Selective Synthesis of Polysubstituted Naphthalenes

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成果类型:
期刊论文
作者:
Shu, Wen-Ming*;Liu, Shan;He, Jian-Xin;Wang, Shuai;Wu, An-Xin*
通讯作者:
Shu, Wen-Ming;Wu, An-Xin
作者机构:
[He, Jian-Xin; Liu, Shan; Wang, Shuai; Shu, Wen-Ming] Yangtze Univ, Coll Chem & Environm Engn, Jingzhou 434023, Peoples R China.
[Wu, An-Xin] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Hubei, Peoples R China.
通讯机构:
[Shu, Wen-Ming] Y
[Wu, An-Xin] C
Yangtze Univ, Coll Chem & Environm Engn, Jingzhou 434023, Peoples R China.
Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Hubei, Peoples R China.
语种:
英文
期刊:
JOURNAL OF ORGANIC CHEMISTRY
ISSN:
0022-3263
年:
2018
卷:
83
期:
16
页码:
9156-9165
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21472056, 21772051]; Doctoral Scientific Research Startup Foundation of Yangtze University [801090010135]; Yangtze Youth Talents Fund [2016cqn25]
机构署名:
本校为通讯机构
院系归属:
化学学院
摘要:
An interesting σ-bond insertion/benzannulation reaction for the synthesis of polysubstituted naphthalene derivatives has been developed from readily accessible ketones, arynes, and alkynoates. This practical and transition-metal-free method provides a novel route to diverse naphthalenes through a substrate-controlled rearrangement re...

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