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Well-defined Co–Pt–OH as “electronic pump” on Co-LDH nanocages for enhanced oxygen evolution reaction

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成果类型:
期刊论文
作者:
Zhang, Shengbo;Zhan, Guangming;Wang, Xiaobing;Cao, Shiyu;Yang, Qifeng;...
通讯作者:
Liu, Xiao;Wang, Hua
作者机构:
[Zhang, Lizhi; Cao, Shiyu; Wang, Xiaobing; Zhang, Shengbo; Zhan, Guangming; Liu, Xiao] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
[Zhu, Xinli; Li, Mei; Yang, Qifeng; Han, Jinyu; Zhang, Shengbo; Wang, Hua; Yang, Leixin] Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn, Sch Chem Engn & Technol, Key Lab Green Chem Technol,Minist Educ, Tianjin 300072, Peoples R China.
通讯机构:
[Liu, Xiao] C
[Wang, Hua] T
Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn, Sch Chem Engn & Technol, Key Lab Green Chem Technol,Minist Educ, Tianjin 300072, Peoples R China.
语种:
英文
关键词:
Co–Pt−OH;Electronic pump;LDH nanocages;Oxygen evolution reaction;Pt nanocluster
期刊:
Applied Catalysis B: Environmental
ISSN:
0926-3373
年:
2020
卷:
269
页码:
118782
基金类别:
We acknowledge the National Natural Science Foundation of China ( 21976066 , U1662109 ) for financial support. The Program of Introducing Talents of Discipline to Universities of China (111 program, B17019) is also acknowledged.
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
The acceleration of electron transfer through the regulation of coordination environment of active sites is an effective way to improve reaction performances. Herein, cobalt layered double hydroxide decorated with sub-1 nm platinum clusters (Pt/Co-LDH) were synthesized for oxygen evolution reaction (OER). The integration of platinum unexpectedly induced unique nanocage structures assembled by ultra-thin LDH nanosheets via an in-situ redox process. The as-prepared Pt/Co-LDH nanocages exhibit high OER activity with a low overpotential of 265 mV a...

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