Porous network of ultrathin V6O13-polyoxometalates nanosheets grown on carbon cloth as anode materials for high-performance lithium-ion batteries

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成果类型：

期刊论文

作者：

Liu, Gaofu;Zhang, Ruixiao;Sheng, Zhuwei;Chen, Mingyue;Qi, Pengcheng;...

通讯作者：

Yiwen Tang

作者机构：

[Chen, Mingyue; Tang, Yiwen; Qi, Pengcheng; Liu, Gaofu; Wu, Hao; Sheng, Zhuwei; Zhang, Ruixiao; Wu, Xiaoyan; Lu, Yu; Li, Wenhui] Cent China Normal Univ, Inst Nanosci & Technol, Coll Phys Sci & Technol, Wuhan 430079, Peoples R China.

[Liu, Gaofu] Guizhou Educ Univ, Sch Phys & Elect Sci, Guiyang 550018, Peoples R China.

[Zou, Xuefeng] Guizhou Educ Univ, Guizhou Prov Key Lab Computat Nanomat Sci, Guiyang 550018, Peoples R China.

通讯机构：

[Yiwen Tang] I

Institute of Nano-Science and Technology, College of Physical Science and Technology, Central China Normal University, Wuhan 430079, China

语种：

英文

关键词：

Anodes;Carbon;Ions;Lithium-ion batteries;Molybdenum oxide;Morphology;Oxides;Anode material;Carbon cloths;High-performance lithium-ion batteries;One pot;Phosphotungstic acid;Polyoxometalates;Porous networks;Ultra-thin;V6O13-polyoxometalate nanosheet;Variable structures;Nanosheets

期刊：

Journal of Alloys and Compounds

ISSN：

0925-8388

年：

2023

卷：

937

页码：

168474

DOI：

10.1016/j.jallcom.2022.168474

基金类别：

The authors acknowledge the financial support of the National Natural Science Foundation of China (Grant Nos. 51972133 , 51572102 ), Excellent innovative project with PhD in College of Physical Science and Technology of Central China Normal University, First-Rate Professional Physics in Guizhou Province (JGT [2019] No. 46 ) and Scientific Research Fund project of Guizhou Education University (Grant No. 2021ZD002 ).

机构署名：

本校为第一机构

院系归属：

物理科学与技术学院

摘要：

Polyoxometalates (POM) have a wide range of applications in electrochemistry, catalysis, and energy storage due to their variable structure and nature. Here, we designed a novel 3D porous network of ultrathin V6O13- POM nanosheets on carbon cloth (V6O13-POM//CC) for the first time by one-pot hydrothermal method with the help of phosphotungstic acid. Serving as inorganic ligands, the anions of phosphotungstic acid co-ordinate with V cations, facilitating the assembly of nanoclusters and guiding to control of the morphology of V6O13-POM composites, which increases the specific surface area and m...

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Porous network of ultrathin V6O13-polyoxometalates nanosheets grown on carbon cloth as anode materials for high-performance lithium-ion batteries

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