The purification of water and air by semiconductor photocatalysis is a rapidly growing area for academic research and industrial innovation, featured with ambient removal of organic or inorganic pollutants by using solar light as the energy source and atmospheric O2 as the green oxidant. Both charge transfer and energy transfer from excited photocatalysts can overcome the spin-forbidden nature of O2. Layered bismuth oxyhalides are a new group of two-dimensional photocatalysts with an appealing geometric and surface structure that allows the dyn...