期刊论文

中文

化学试剂

0258-3283

1996

18

2

70-72

10.13822/j.cnki.hxsj.1996.02.003

湖北省自然科学基金；

本校为第一机构

磷试剂α-羟基烃基膦酸酯1与氯乙酰氯反应制得α-(氯代乙酰氧基)烃基膦酸酯2, 进而又和邻甲基苯硫酚进行缩合反应,合成了8种新型的α-(邻甲苯硫基乙酰氧基)烃基膦酸酯, 收率为80%-90%。通过元素分析、IR及1HNMR确证了化合物的结构。

Eight title compounds were synthesized by condensation of α-(chloroacetoxy) alkyl phosphonate ando-tolylthiol in good yields using potassium iodide andtetrabutyl ammonium bromide as catalysts and acetoneas solvent in the presence of potassium carbonate. Allnew compounds have been identi...