Two new β-diketones containing trifluoromethyl groups, 4,4,4-trifluoro-1-( 6-methoxynaphthalen-2-yl ) butane-1, 3-dione and 4,4,4-trifluoro-1-( 4-phenylmethoxyphenyl ) butane-1,3-dione were synthesized from aromatic ketones and ethyl tri-fluoracetate by the classical Claisen condensation reaction using CH3ONa as the strong base. Their structures were determined by means of IR, 1^ HNMR, MS spectra and elemental analysis. The resuits showed that the two β-diketones containing the trifluoromethyl group almost comp...