期刊论文

Lu, Liang-Qiu;Xiao, Wen-Jing

英文

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

1433-7851

2019

58

38

13375-13379

10.1002/anie.201907478

National Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21822103, 21820102003, 21772052, 21772053]; Program of Introducing Talents of Discipline to Universities of China (111 Program) [B17019]; Natural Science Foundation of Hubei ProvinceNatural Science Foundation of Hubei Province [2017AHB047]; International Joint Research Center for Intelligent Biosensing Technology and Health

本校为第一且通讯机构

Chiral catalysts tolerating photochemical reactions are in great demand for the vast development of visible-light-induced asymmetric synthesis. Now, chiral octahedral complexes based on earth-abundant metal and chiral N4 ligands are reported. One well-defined chiral CoII-complex is shown to be an efficient catalyst in the visible-light-induced conjugated addition of enones by alkyl and acyl radicals, providing synthetically valued chiral ketones and 1,4-dicarbonyls in 47–'99 % yields with up to 9...