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Visible Light-Driven Radical-Mediated C-C Bond Cleavage/Functionalization in Organic Synthesis

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成果类型:
期刊论文
作者:
Yu, Xiao-Ye;Chen, Jia-Rong*;Xiao, Wen-Jing*
通讯作者:
Chen, Jia-Rong;Xiao, Wen-Jing
作者机构:
[Chen, Jia-Rong; Xiao, WJ; Xiao, Wen-Jing; Yu, Xiao-Ye] Cent China Normal Univ, Coll Chem, CCNU uOttawa Joint Res Ctr, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Hubei, Peoples R China.
通讯机构:
[Chen, JR; Xiao, WJ] C
Cent China Normal Univ, Coll Chem, CCNU uOttawa Joint Res Ctr, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Hubei, Peoples R China.
语种:
英文
期刊:
Chemical Reviews
ISSN:
0009-2665
年:
2021
卷:
121
期:
1
页码:
506-561
基金类别:
We are sincerely grateful to our collaborators and co-workers, whose names appear in the related references, for their significant contributions to our study. The authors’ works in this area have been sponsored by the National Natural Science Foundation of China (91856119, 21971081, 21622201, 21820102003, 91956201, and 21772053), the Science and Technology Department of Hubei Province (2017AHB047), the Fundamental Research Funds for the Central Universities (CCNU19TS051), and the Program of Introducing Talents of Discipline to Universities of China (111 Program, B17019); their support is gratefully acknowledged. We also thank all of the anonymous referees for their invaluable suggestions and comments on preparing this manuscript.
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
Thermal C-C bond cleavage reactions allow the construction of structurally diverse molecular skeletons via predictable and efficient bond reorganizations. Visible light photoredox-catalyzed radical-mediated C-C bond cleavage reactions have recently emerged as a powerful alternative method for overcoming the thermodynamic and kinetic barrier of C-C bond cleavage in diverse molecular scaffolds. In recent years, a plethora of elegant and useful reactions have been invented, and the products are sometimes otherwise inaccessible by classic thermal r...

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