Vanadium-based oxides cathodes in aqueous Zn ion batteries are being widely investigated. Strategies to improve their electrochemical property are focused on the development of ion insertion/desertion kinetics, and pre-insertion of ions or molecules. However, few works focuses on the pseudocapacitive behaviors vs capacity. In this work, ammonium vanadates with different surface areas and architectures are designed, and it is find that the designed structure electrodes show rather high initial capacities of 574.6 and 524.0 mAh/g at 0.1 A/g, whic...