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Sustainable molecular oxygen activation with oxygen vacancies on the {001} facets of BiOCl nanosheets under solar light

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成果类型:
期刊论文
作者:
Li, Hao;Shi, Jingu;Zhao, Kun;Zhang, Lizhi*
通讯作者:
Zhang, Lizhi
作者机构:
[Zhang, Lizhi; Li, Hao; Shi, Jingu; Zhao, Kun] Cent China Normal Univ, Coll Chem, Inst Environm Chem, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Peoples R China.
通讯机构:
[Zhang, Lizhi] C
Cent China Normal Univ, Coll Chem, Inst Environm Chem, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Peoples R China.
语种:
英文
期刊:
Nanoscale
ISSN:
2040-3364
年:
2014
卷:
6
期:
23
页码:
14168-14173
基金类别:
National Basic Research Program of China (973 Program)National Basic Research Program of China [2013CB632402]; National Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21177048, 51472100]; Natural Science Foundation of Hubei ProvinceNatural Science Foundation of Hubei Province [2013CFA114]; Self-Determined Research Funds of CCNU from the Colleges' Basic Research and Operation of MOE [CCNU14Z01001]; Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
We demonstrate that oxygen vacancies on the {001} facets of BiOCl nanosheets can more sustainably activate molecular oxygen for organic pollutant removal under solar light than the TiO2 counterparts. The oxygen vacancies on the {001} facets of BiOCl nanosheets are effectively refreshed by UV light, and are also responsible for the efficient utilization of visible light to activate molecular oxygen, accounting ...

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