Transition-Metal-Free Coupling Annulation of Arynes with Ketones and Alkynoates: Assembly of Functionalized Naphthalenes

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成果类型：

期刊论文

作者：

Shu, Wen-Ming*;Zheng, Kai-Lu;Ma, Jun-Rui;Wu, An-Xin*（吴安心）

通讯作者：

Shu, Wen-Ming;Wu, An-Xin（吴安心）

作者机构：

[Wu, An-Xin; Ma, Jun-Rui; Zheng, Kai-Lu; Shu, Wen-Ming] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Coll Chem, Wuhan 430079, Hubei, Peoples R China.

[Shu, Wen-Ming] Yangtze Univ, Coll Chem & Environm Engn, Jingzhou 434023, Peoples R China.

通讯机构：

[Shu, WM; Wu, AX] C

[Shu, Wen-Ming] Y

Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Coll Chem, Wuhan 430079, Hubei, Peoples R China.

Yangtze Univ, Coll Chem & Environm Engn, Jingzhou 434023, Peoples R China.

语种：

英文

期刊：

Organic Letters

ISSN：

1523-7060

年：

2016

卷：

期：

页码：

3762-3765

DOI：

10.1021/acs.orglett.6b01782

基金类别：

National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21272085, 21472056]; Fundamental Research Funds for Central UniversitiesFundamental Research Funds for the Central Universities [CCNU15ZX002]; Central China Normal University [2015YBYB065]

机构署名：

本校为第一且通讯机构

院系归属：

化学学院

摘要：

A transition-metal-free coupling annulation reaction of arynes, ketones, and alkynoates has been demonstrated. Using this formal [2 + 2 + 2] cycloaddition reaction, a wide variety of naphthalene derivatives were conveniently constructed in one pot with high efficiency. In addition, this novel and valid annulation has been successfully applied to the s...

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Transition-Metal-Free Coupling Annulation of Arynes with Ketones and Alkynoates: Assembly of Functionalized Naphthalenes

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