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CO oxidation over CuOx/TiO2 catalyst: The importance of oxygen vacancies and Cu+ species

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成果类型:
期刊论文
作者:
Chen, Wei;Xu, Jue;Huang, Fajun;Zhao, Chaoying;Guan, Yingqiao;...
通讯作者:
Luo, Zhu(luo.z@mail.ccnu.edu.cn)
作者机构:
[Chen, Wei; Huang, Fajun; Luo, Zhu; Yang, Weiwei; Zhao, Chaoying; Guo, Yanbing; Guan, Yingqiao; Xu, Jue; Fang, Yarong] Cent China Normal Univ, Inst Environm & Appl Chem, Coll Chem, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Peoples R China.
[Hu, Jinpeng] Fujian Longxin 3D Array Technol Co Ltd, Longyan 364000, Peoples R China.
通讯机构:
[Zhu Luo; Yanbing Guo] K
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Environmental and Applied Chemistry, College of Chemistry, Central China Normal University, Wuhan 430079, PR China
语种:
英文
关键词:
Oxygen vacancies;Cu plus;brookiteTiO2;CO oxidation
期刊:
Applied Surface Science
ISSN:
0169-4332
年:
2023
卷:
618
页码:
156539
基金类别:
The authors are grateful for the financial support from the National Natural Science Foundation of China (No. 22076060, 21777051, 51702112, 21707039), The Recruitment Program of Global Young Experts start-up funds, The Program of Introducing Talents of Discipline to Universities of China (111 program, B17019) and National Engineering Laboratory for Mobile Source Emission Control Technology (NELM-S2017A11, NELMS2018A08). Distinguished Young Scholars of Hubei Natural Science Foundation (2021CFA085). Science and Technology Program of Longyan (No. 2021LYF9009).
机构署名:
本校为第一机构
院系归属:
化学学院
摘要:
It is well documented that the existence of oxygen vacancies and active Cu species can improve CO oxidation activity over TiO2 substrate. Herein, TiO2-supported copper catalysts (CuOx/TiO2) with different ratio of oxygen vacancies (Ov) and Cu+ has been synthesized. The existence and amount of Ov and Cu+ species were characterized by transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and electron paramagnetic resonance spectrum (EPR). The synergetic effect between Cu+ and oxygen vacancies was investigated in terms of ...

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