National Natural Science Foundation of ChinaNational Natural Science Foundation of China [21772054, 21472059]; 111 ProjectMinistry of Education, China - 111 Project [B17019]
机构署名：
本校为第一且通讯机构
院系归属：
化学学院
摘要：
Novel classes of contorted hexabenzocoronenes (c-HBCs) which exhibit a doubly concave configuration were synthesized by using hexabenzocoronene as bridge ligand and diphenylamine/triphenylamine as the redox-active termini. Although the analysis of the crystal structures of tri-di(4-methoxyphenyl) amino-substituted HBC (1), trimethoxy-substituted HBC (3) and tri(triphenylamine)-substituted HBC (4) show that the peripheral modified arylamine groups have a certain influence on the interaction force between molecules, the results of UV-vis absorption and fluorescence emission spectra indicate that...
