期刊论文

中文

华中师范大学学报(自然科学版)

1000-1190

2006

40

1

55-57

10.19603/j.cnki.1000-1190.2006.01.015

湖北省教育厅资助项目（20040131）；

本校为第一机构

合成了3，5-二溴水杨醛水杨酰腙配体及其金属锌、铜、镍的配合物，培养出锌配合物晶体．通过测定配体和配合物的元素分析、红外光谱、电子光谱、摩尔电导、质谱和核磁共振及锌配合物晶体，确定为六配位化合物，其中溶剂分子参与了配位．并对锌配合物晶体的结构特征进行了分析．

The complexes of copper, zinc, nickel with 3,5-dibromosalicylaldehyde salicylhydrazone were synthesized in DMF and pyridine. The crystal of zinc complex with 3,5-dibromosalicylaldehyde salicylhydrazone was obtained. Their six-coordinated forms which included solvent molecules were confirmed by their elemental analysis, IR, UV, conductivity, electronic spectra, MS, 1H NMR and X-ray diffraction. T...