Atomic-Layered Cu5 Nanoclusters on FeS2 with Dual Catalytic Sites for Efficient and Selective H2O2 Activation

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作者信息关键词期刊信息基础信息归属信息摘要

成果类型：

期刊论文

作者：

Ling, Cancan;Liu, Xiufan;Li, Hao*;Wang, Xiaobing;Gu, Huayu;...

通讯作者：

Zhang, LZ;Li, Hao

作者机构：

[Wei, Kai; Liang, Chuan; Zhang, Lizhi; Ben, Haijie; Shi, Yanbiao; Wang, Xiaobing; Shen, Wenjuan; Li, Yaling; Zhang, LZ; Gu, Huayu; Ling, Cancan; Liu, Xiufan; Zhao, Jincai; Zhan, Guangming; Li, Meiqi] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Inst Appl & Environm Chem, Coll Chem,Minist Educ, Wuhan 430079, Peoples R China.

[Zhang, Lizhi; Shi, Yanbiao; Li, Hao; Li, H; Zhang, LZ] Shanghai Jiao Tong Univ, Sch Environm Sci & Engn, Shanghai 200240, Peoples R China.

通讯机构：

[Li, H] S

[Zhang, LZ ] C

Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Inst Appl & Environm Chem, Coll Chem,Minist Educ, Wuhan 430079, Peoples R China.

Shanghai Jiao Tong Univ, Sch Environm Sci & Engn, Shanghai 200240, Peoples R China.

语种：

英文

关键词：

Catalysis;Environmental Control;Fenton Reaction;H2O2 Activation;Reactive Oxygen Species

期刊：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

ISSN：

1433-7851

年：

2022

卷：

期：

页码：

e202200670-

DOI：

10.1002/anie.202200670

基金类别：

This work was financially supported by National Key Research and Development Program of China (Grant 2018YFC1800701), and the National Natural Science Foundation of China (Grant 21936003, 21872061, 21976066 and 21906126). We thank the National Supercomputer Center in Jinan for providing high performance computation, and National Synchrotron Radiation Laboratory in Beijing and Hefei for the characterization.

机构署名：

本校为第一且通讯机构

院系归属：

化学学院

摘要：

Regulating the distribution of reactive oxygen species generated from H2O2 activation is the prerequisite to ensuring the efficient and safe use of H2O2 in the chemistry and life science fields. Herein, we demonstrate that constructing a dual Cu−Fe site through the self-assembly of single-atomic-layered Cu5 nanoclusters onto a FeS2 surface achieves selective H2O2 activation with high efficiency. Unlike its unitary Cu or Fe counterpart, the dual Cu−Fe sites residing at the perimeter zone of the Cu5/FeS2 interface facilitate H2O2 adsorption and...

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Atomic-Layered Cu5 Nanoclusters on FeS2 with Dual Catalytic Sites for Efficient and Selective H2O2 Activation

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