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Synthesis and performance of a novel nitrogen-containing cyclic phosphate for intumescent flame retardant and its application in epoxy resin

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成果类型:
期刊论文
作者:
You, Geyun;Cheng, Zhiquan;Peng, Hao;He, Hongwu*
通讯作者:
He, Hongwu
作者机构:
[He, Hongwu; Peng, Hao; You, Geyun; Cheng, Zhiquan] Cent China Normal Univ, Inst Organ Synth, Coll Chem, Wuhan 430079, Peoples R China.
通讯机构:
[He, Hongwu] C
Cent China Normal Univ, Inst Organ Synth, Coll Chem, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
flame retardance;mechanical properties;resins;synthesis and processing;thermal properties
期刊:
Journal of Applied Polymer Science
ISSN:
0021-8995
年:
2015
卷:
132
期:
16
页码:
n/a-n/a
基金类别:
National Engineering and Technology Center the Development and Utilization of Phosphor Resources [2012k011]
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
ABSTRACT A novel nitrogen‐containing cyclic phosphate (NDP) was synthesized and well characterized by 1H, 13C, 31P NMR, mass spectra and elemental analysis. NDP was used as an additive intumescent flame retardant (AIFR) to impart flame retardancy and dripping resistance for diglycidyl ether of bisphenol‐A epoxy resin (DGEBA) curied by 4,4′‐diaminodiphenylsulfone (DDS) with different phosphorus content. The flammability, thermal stability, and mechanical properties of NDP modified DGEBA/DDS thermosets were investigated by UL‐94 vertical bur...

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