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Direct conversion of aromatic ketones to arenecarboxylic esters via carbon-carbon bond-cleavage reactions

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成果类型:
期刊论文
作者:
Yin, Guodong;Gao, Meng;Wang, Zihua;Wu, Yandong;Wu, Anxin*吴安心
通讯作者:
Wu, Anxin
作者机构:
[Wu, Anxin; Yin, Guodong; Gao, Meng; Wang, Zihua] Cent China Normal Univ, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
[Wu, Yandong] Xiangtan Univ, Coll Chem, Xiangtan 411105, Peoples R China.
通讯机构:
[Wu, Anxin] C
Cent China Normal Univ, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
语种:
英文
期刊:
Bulletin of the Chemical Society of Japan
ISSN:
0009-2673
年:
2008
卷:
81
期:
3
页码:
369-372
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
Aromatic methyl ketones, ß-keto esters, and trifluoromethyl-l,3- diketones can be directly converted to arene-carboxylic esters via carbon-carbon bond cleavage of pyridinium iodide intermediates in the presence of copper(II) oxide, iodine, pyridine, and potassium carbonate in alcoholic media. The advantages of the present method in terms of good yields, mild reaction conditions, and inexpensive reagents should make this protocol a valuable alternative to ...

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