A General Copper-Box System for the Asymmetric Arylative Functionalization of Benzylic, Propargylic or Allenylic Radicals.

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成果类型：

期刊论文

作者：

Wang, Peng-Zi;Zhang, Zhihan;Jiang, Min;Chen, Jia-Rong;Xiao, Wen-Jing

作者机构：

[Wang, Peng-Zi] Central China Normal University, College of Chemistry, 152 Luoyu Road, Wuhan, CHINA

[Zhang, Zhihan] Central China Normal University, College of Chemistry, CHINA

[Jiang, Min] Hangzhou Normal University, College of Materials, Chemistry and Chemical Engineering, CHINA

[Chen, Jia-Rong] Central China Normal University, College of Chemistry, 430079, Wuhan, CHINA

[Xiao, Wen-Jing] Central China Normal University, College of Chemistry, 152 Luoyu Road, 430079, Wuhan, CHINA

语种：

英文

关键词：

Arylation;asymmetric radical coupling;copper catalysis;photoredox catalysis

期刊：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

ISSN：

1433-7851

年：

2024

页码：

e202411469

DOI：

10.1002/anie.202411469

机构署名：

本校为第一机构

院系归属：

化学学院

摘要：

Radical-involved arylative cross-coupling reactions have recently emerged as an attractive strategy to access valuable aryl-substituted motifs. However, there still exist several challenges such as limited scope of radical precursors/acceptors, and lack of general asymmetric catalytic systems, especially regarding the multicomponent variants. Herein, we reported a general copper-Box system for asymmetric three-component arylative radical cross-coupling of vinylarenes and 1,3-enynes, with oxime carbonates and aryl boronic acids. The reactions proceed under practical conditions in the absence or...

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A General Copper-Box System for the Asymmetric Arylative Functionalization of Benzylic, Propargylic or Allenylic Radicals.

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