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Donor-σ-acceptor molecules with alkyl σ-linkers of different lengths: Exploration on the exciplex emission and their use for efficient organic light-emitting diodes

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成果类型:
期刊论文
作者:
Song, Yongjun;Yu, Renyou;Meng, Xianwen;He, Lei
通讯作者:
He, Lei(helei@ccnu.edu.cn)
作者机构:
[Song, Yongjun; Meng, Xianwen; He, Lei; Yu, Renyou] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ,Hubei Int Sci & Technol Cooperat Base, Wuhan 430079, Peoples R China.
[He, Lei] South China Univ Technol, State Key Lab Luminescent Mat & Devices, Guangzhou 510640, Peoples R China.
通讯机构:
[Lei He] K
Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, Hubei International Scientific and Technological Cooperation Base of Pesticide and Green Synthesis, College of Chemistry, Central China Normal University, Wuhan, 430079, PR China<&wdkj&>State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou, 510640, PR China
语种:
英文
关键词:
Donor-σ-acceptor;Alkyl linker;Exciplex;Thermally-activated delayed fluorescence;Organic light-emitting diodes
期刊:
Dyes and Pigments
ISSN:
0143-7208
年:
2023
卷:
208
页码:
110876
基金类别:
Fundamental Research Funds for the Central Universities [CCNU22QN008]; Open Fund of the State Key Laboratory of Luminescent Materials and Devices (South China University of Technology) [2022-skllmd-22]; Program of Introducing Talents of Discipline to Universities of China [B17019]
机构署名:
本校为第一机构
院系归属:
化学学院
摘要:
Donor-σ-acceptor molecules featuring exciplex emission have been extensively researched for developing thermally-activated delayed fluorescence; however, varying the length of alkyl σ-linker to explore the exciplex emission and to develop efficient exciplex emitters has not been fully conducted. Herein, we report donor-σ-acceptor exciplex emitters (1–3) developed with 9,9-dimethyl-10-phenyl-9,10-dihydroacridine donor, 2,4,6-triphenyl-1,3,5-triazine acceptor, and alkyl σ-linkers of different lengths (−CH2− for 1, –CH2CH2− for 2, and –C...

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