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New structure of electrical double layer to modify triple-layer model at oxide-water interface

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成果类型:
期刊论文
作者:
Shuai, Xiufu
通讯作者:
Xiufu Shuai
作者机构:
[Shuai, Xiufu] Cent China Normal Univ, Sch Urban & Environm Sci, Hubei Prov Key Lab Geog Proc Anal & Simulat, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China.
通讯机构:
[Xiufu Shuai] H
Hubei Province Key Lab. for Geographical Process Analysis and Simulation, School of Urban and Environmental Science, Central China Normal Univ, Wuhan, China
语种:
英文
关键词:
DLM;CCM;Electrical circuit theory;Characteristic relationship;Ion size factor
期刊:
Journal of Soils and Sediments
ISSN:
1439-0108
年:
2023
卷:
23
期:
2
页码:
880-890
机构署名:
本校为第一机构
院系归属:
城市与环境科学学院
摘要:
Purpose Triple-layer model (TLM) is distinct from other surface complexation models (SCMs) with the charged beta-layer between solid surface and diffuse layer. However, its structure of electrical double layer, i.e., three capacitors connected in series, produced an uncharged beta-layer according to the rule of capacitors in the electrical circuit theory. The objective of this study was to modify TLM with the development of a new structure of electrical double layer and mathematical models for the charge-potential relationships. Methods The rule of capacitors in the electrical circuit theory w...

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