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An Efficient Method for the Selective Iodination of alpha,beta-Unsaturated Ketones

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成果类型:
期刊论文
作者:
Wang, Zihua;Yin, Guodong;Qin, Jing;Gao, Meng;Cao, Liping;...
通讯作者:
Wu, Anxin(吴安心
作者机构:
[Wu, Anxin; Yin, Guodong; Cao, Liping; Gao, Meng; Qin, Jing; Wang, Zihua] Cent China Normal Univ, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
通讯机构:
[Wu, Anxin] C
Cent China Normal Univ, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
iodination;alpha,beta-unsaturated ketones;alpha,beta-unsaturated alpha '-iodo ketones;self-sorting
期刊:
SYNTHESIS-STUTTGART
ISSN:
0039-7881
年:
2008
卷:
2008
期:
22
页码:
3675-3681
基金类别:
National Natural Science Foundation of China [20672042, 20872042]; Graduate's Innovation Fund of Central China Normal University
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
An efficient approach to alpha,beta-unsaturated alpha'-iodo ketones directly from alpha,beta-unsaturated ketones by selective iodination at the alpha'-position, without effect on the double bond and the activated benzene ring, in the presence of copper(II) oxide/iodine is described. The present method has the advantages of high yields, short reaction times, inexpensive reagents, mild reaction conditions, ease of ma...

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