Oxidized divinyl oligoacene-bridged diruthenium complexes: Bridged localized radical characters and reduced aromaticity in bridge cores

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成果类型：

期刊论文

作者：

Ou, Ya-Ping;Zhang, Jing;Hu, Yuxuan;Yin, Jun;Chi, Chunyan;...

通讯作者：

Liu, Sheng Hua

作者机构：

[Ou, Ya-Ping] Hengyang Normal Univ, Key Lab Funct Met Organ Cpds Hunan Prov, Key Lab Funct Organometall Mat, Hunan Prov Coll,Coll Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.

[Ou, Ya-Ping; Zhang, Jing; Liu, Sheng Hua; Hu, Yuxuan; Yin, Jun] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.

[Ou, Ya-Ping; Chi, Chunyan] Natl Univ Singapore, Dept Chem, 3 Sci Dr 3, Singapore 117543, Singapore.

通讯机构：

[Liu, Sheng Hua] C

Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.

语种：

英文

期刊：

DALTON TRANSACTIONS

ISSN：

1477-9226

年：

2020

卷：

期：

页码：

16877-16886

DOI：

10.1039/d0dt02883e

基金类别：

National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21772054, 21602049]; Natural Science Foundation of Hunan Province, ChinaNatural Science Foundation of Hunan Province [2017JJ3004]; Study Abroad Fund of China Scholarship Council; Opening Subjects of Hunan Province Key Laboratory of Functional Metal-Organic Compounds [MO19K04]; Aid Programs for Technology Innovative Team and Key Discipline in Education Department of Hunan Province; Support Plan for Talents at Hengyang Normal University

机构署名：

本校为通讯机构

院系归属：

化学学院

摘要：

A series of bimetallic ruthenium vinyl complexes 1-5 bridged by oligoacenes were synthesized and characterized in this study. Comparative cyclic voltammetry results from 1-5 indicated that the first oxidation potential decreased gradually with the extension of conjugate ligands. Upon oxidation to singly oxidized species 1+-5+, rather small ν(CO) changes in the infrared (IR) spectra and the characteristic bands of metal-to-ligand charge transfer absorptions in the near IR (NIR) region predicted via time-dependent DFT calculations suggested that...

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Oxidized divinyl oligoacene-bridged diruthenium complexes: Bridged localized radical characters and reduced aromaticity in bridge cores

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