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Iron Single-Atom Catalysts Boost Photoelectrochemical Detection by Integrating Interfacial Oxygen Reduction and Enzyme-Mimicking Activity

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成果类型:
期刊论文
作者:
Qin, Ying;Wen, Jing;Wang, Xiaosi;Jiao, Lei;Wei, Xiaoqian;...
通讯作者:
Gu, Wenling;Zhu, CZ;Hu, LY
作者机构:
[Qin, Ying; Zhu, Chengzhou; Li, Jinli; Jiao, Lei; Gu, Wenling; Liu, Mingwang; Wang, Xiaosi; Wei, Xiaoqian; Gu, WL; Zhu, CZ; Wang, Hengjia] Cent China Normal Univ, Coll Chem, Int Joint Res Ctr Intelligent Biosensing Technol, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Peoples R China.
[Wen, Jing; Hu, Liuyong] Wuhan Inst Technol, Hubei Engn Technol Res Ctr Optoelect & New Energy, Hubei Key Lab Plasma Chem & Adv Mat, Wuhan 430205, Peoples R China.
[Zheng, Lirong] Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China.
通讯机构:
[Hu, LY ] W
[Gu, WL; Zhu, CZ ] C
Cent China Normal Univ, Coll Chem, Int Joint Res Ctr Intelligent Biosensing Technol, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Peoples R China.
Wuhan Inst Technol, Hubei Engn Technol Res Ctr Optoelect & New Energy, Hubei Key Lab Plasma Chem & Adv Mat, Wuhan 430205, Peoples R China.
语种:
英文
关键词:
photoelectrochemical analysis;single-atom catalysts;nanozymes;oxygen reduction reaction;signal amplification
期刊:
ACS Nano
ISSN:
1936-0851
年:
2022
卷:
16
期:
2
页码:
2997-3007
基金类别:
We gratefully acknowledge the financially support by the National Natural Science Foundation of China (Grant Nos. 22104114, 22074049, and 22004042), the Fundamental Research Funds for the Central Universities (Grant Nos. CCNU20QN007 and CCNU20TS013), and the Program of Introducing Talents of Discipline to Universities of China (111 program, Grant No. B17019). This work was carried out with the support of the 1W1B beamline at the Beijing Synchrotron Radiation Facility.
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
The investigations on the generation, separation, and interfacial-redox-reaction processes of the photoinduced carriers are of paramount importance for realizing efficient photoelectrochemical (PEC) detection. However, the sluggish interfacial reactions of the photogenerated carriers, combined with the need for appropriate photoactive layers for sensing, remain challenges for the construction of advanced PEC platforms. Here, as a proof of concept, well-defined Fe single-atom catalysts (Fe SACs) were integrated on the surface of semiconductors, ...

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