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Ascorbic acid enhanced activation of oxygen by ferrous iron: A case of aerobic degradation of rhodamine B

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成果类型:
期刊论文
作者:
Hou, Xiaojing;Shen, Wenjuan;Huang, Xiaopeng;Ai, Zhihui*;Zhang, Lizhi
通讯作者:
Ai, Zhihui
作者机构:
[Zhang, Lizhi; Hou, Xiaojing; Huang, Xiaopeng; Shen, Wenjuan; Ai, Zhihui] Cent China Normal Univ, Inst Environm Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
通讯机构:
[Ai, Zhihui] C
Cent China Normal Univ, Inst Environm Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
Ascorbic acid;Ferrous ions;Oxygen activation;ROS;Rhodamine B
期刊:
Journal of Hazardous Materials
ISSN:
0304-3894
年:
2016
卷:
308
页码:
67-74
基金类别:
National Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21173093, 21177048, 21477044]; Natural Science Foundation of Hubei ProvinceNatural Science Foundation of Hubei Province [2013CFA114]; Self-Determined Research Funds of CCNU from Colleges' Basic Research and Operation of MOE [CCNU14Z01001, CCNU14KFY002]
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
Molecular oxygen activation by ferrous ions (Fe(II)) in aqueous solution could generate reactive oxygen species (ROS) with high oxidation potential via reaction between Fe(II) and oxygen molecules (Fe(II)/air), however, ROS yielded in the Fe(II)/air process is insufficient for removal of organic pollutants due to the irreversible ferric ions (Fe(III)) accumulation. In this study, we demonstrate that ascorbic acid (AA) could enhance ROS generation via oxygen activation by ferrous irons (AA/Fe(II)/air) and thus improve the degradation of rhodamine (RhB) significantly. It was found that the first...

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