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Conversion of lignin into light olefins and aromatics over Fe/ZSM-5 catalytic fast pyrolysis: Significance of Fe contents and temperature

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成果类型:
期刊论文
作者:
Yang, Mingfa;Shao, Jingai*;Yang, Zixu;Yang, Haiping;Wang, Xianhua;...
通讯作者:
Shao, Jingai
作者机构:
[Wang, Xianhua; Yang, Haiping; Chen, Hanping; Yang, Mingfa; Shao, Jingai] Huazhong Univ Sci & Technol, Sch Energy & Power Engn, State Key Lab Coal Combust, Wuhan 430074, Hubei, Peoples R China.
[Chen, Hanping; Shao, Jingai] Huazhong Univ Sci & Technol, Sch Energy & Power Engn, Dept New Energy Sci & Engn, Wuhan 430074, Hubei, Peoples R China.
[Yang, Zixu] East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China.
[Wu, Zhengshun] Cent China Normal Univ, Chem Coll, Wuhan 430079, Hubei, Peoples R China.
通讯机构:
[Shao, Jingai] H
Huazhong Univ Sci & Technol, Sch Energy & Power Engn, State Key Lab Coal Combust, Wuhan 430074, Hubei, Peoples R China.
语种:
英文
关键词:
Aromatic;Catalytic pyrolysis;Fe/ZSM-5;Light olefin;Lignin
期刊:
Journal of Analytical and Applied Pyrolysis
ISSN:
0165-2370
年:
2019
卷:
137
页码:
259-265
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51506071, 51676081]
机构署名:
本校为其他机构
院系归属:
化学学院
摘要:
The conversion of lignin into light olefins and aromatic compounds via catalytic fast pyrolysis was performed in a fixed bed reactor over a range of Fe-modified ZSM-5 catalysts at different temperatures. More specifically, catalysts containing 0, 1, 3, 6, and 9 wt.% Fe were prepared by an impregnation method, and the resulting catalysts were characterized by XRD, NH 3 -TPD, H 2 -TPR and BET analysis. The catalyst structure remained intact upon increasing the Fe loading, although the surface area, pore volume, and number of acidic sites of the c...

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